Chemical Hazards
Average annual world production of chemicals amounts to an estimated 400 million tones. There are between 5 to 7 million known chemicals, however, only 70,000 to 80,000 are on the market, with 1,000 or so being produced in substantial quantities. In North America around 1,000 to 1,200 are produced annually (50 % are polymers).In Western Europe, some 150 to 200 new substances are registered each year. Of the 70,000 to 80,000 chemicals only 5 to 10% ( i.e., 500 to 7,000 should be considered hazardous; 150 to 200 of these are carcinogenic.
Hazardous Substances are used in many workplaces and take many different forms. Solids, liquids, gases, mists and fumes can be present in the workplace.
Chemical hazards are dependent on:
- Amount
- Concentration
- Time of exposure
- Mode of entry to the body
- Age
- Sex
- Health status
- Resistance of the exposed workers
The effects of chemical agents are as follows:
- Asphyxiation
- Systemic intoxication
- Pneumoconiosis
- Carcinogens
- Irritation
- Mutagencity
- Teratogenicity
Dangerous Chemical Substances
Many dangerous substances are used in industry, commerce, agriculture, research activities, hospitals and teaching establishments.
The classification of dangerous substances is based largely on the characteristic properties of such substances and their effects on man. Legislation on this subject also requires the provision of a specific pictorial symbol on any container or package.
The following terms are used in the classification of dangerous substances in the classification, packing and labeling of dangerous substances regulations 1984.
A. Corrosion
B. Oxidizing
C. Harmful
D. Very toxic and toxic
E. Irritant
F. Highly flammable
G. Explosive
A. Corrosive
Hazard: Living tissues as well as equipment are destroyed on contact with these chemicals.
Caution: Do not breathe vapors and avoid contact with skin eyes, and clothing
B. Oxidizing
Hazard: ignite combustible material or worsen existing fire and thus make fire fighting more difficult.
Caution: Keep away from combustible material. Restrict smoking in that area.
C. Harmful
Hazard: Inhalation and insertion of or skin penetration by these substances is harmful to heath.
Caution: Avoid contact with the human body, including inhalation of vapors and in cases of malaise consult doctor.
D. Very toxic and toxic
Hazard: The substances are very hazardous to health whether breathed, swallowed or in contact with the skin and may even lead to death.
Caution: Avoid contact with human body, and immediately consult a doctor in case of malaise.
E. Irritant
Hazard: May have an irritant effect on skin, eyes and respiratory organs
Caution: Do not breathe vapors and avoid contact with skin and eye
F. Highly Flammable
Hazard: Substances with flash point less than 60'C or 140'F
Caution: keep away source of ignition.
G. Explosive
Hazard: Substances which may explode under certain condition
Caution: Avoid shock, friction, sparks and heat.
Chemical Hazards Evaluation
- Toxicity assessment
- Work activity/risk assessment evaluation
- Assessment of controls effectiveness to block routes of entry
- Exposure monitoring
- Recommendations for improvement
Chemical Hazards: Exposure Monitoring
- Special instruments - infrared absorption, photoionization, gas Chromatography
- Detector tubes
- Air sampling and lab analysis
- Professional judgment
Chemical Hazards: Engineering Controls
- Substitution (use lower toxicity materials)
- Enclose processes and otherwise engineer for low emission / low risk
- Provide local exhaust to remove airborne agents
- Local exhaust ventilation
- Need to have even air flow for hoods
- Need to design for adequate capture velocity -usually about 100 feet/minute
- Need sufficient make up air
- Use ACGIH Ventilation Manual for design
- Reduce exposure time
- Better procedures
- Training
- PPE - gloves, face shields, respirators
- Remote Operation